Synthesis And Characterization Of Strontium Ferrite Environmental Sciences Essay

Synthesis And Characterization Of strontium Ferrite Environmental Sciences EssayStrontium ferrite is a ferro attractive forceic material and reported as having hexagonal magnetoplumbite type (M-type) body structure. It is the most widely use permanent magnets throughout the world, which account for about 90wt% of the annual production of permanent magnets. In this study, the strontium ferrite is synthe surfaced utilise sol- gelatin methods and the charismatic properties were analyzed.Chapter 1 gave introduction about the structure of M-type hexagonal strontium ferrite. Besides, some general magnetised properties will be discussed. technical applications of strontium ferrite would be discussed as well.Chapter 2 is every(prenominal) about the experimental details, including the synthetic proficiencys used for strontium ferrite, description of instrument used and outgrowths carried out.Chapter 3 gruelling on the results on magnetic faculty of hexagonal strontium ferrite. Comp arison between strontium ferrite and cation-substituted strontium ferrite was do.Chapter 4 concluded the whole investigation of this study. Suggestions for upcoming studies were also discussed. Better understanding of the properties and practical applications of strontium ferrite can be achieved through this study.ABSTRACTThe properties of magnetoplumbite type (M-type) hexagonal strontium ferrite has been investigated. The attempt of alternate of conscientious objector(II) oxide and titanium(IV) oxide in order to produce a quaternary system of the type SrO-Fe2O3-XO where X represents the dopant cation was made. The implication is based on sol-gel method where ethylene ethylene glycol is the gel precursor. This technique was employed because it was found to be able to produce nanoparticles of cation substituted strontium ferrite. Moreover, sol-gel method can produce spirited yields of strontium ferrite particles.Overall, the magnetic properties were observed to be castrate su bsequently the cation substitution. Co(II)-Ti(IV) substitution in SrFe12O19 with different ratios were made in this study to investigate the doing of cation substitution in magnetic properties of strontium ferrite. Co(II)-Ti(IV) substitution in strontium ferrite with bulwarke ratio of 0.4 showed the ruff magnetic properties that we desired for. The mass susceptibility where X = 0.4 was found to be increase sharply compargond to the unsubstituted one. Except the cobalt titanium substitution with groynee ratio of 0.4, other cation substitution ratios showed decrease in mass susceptibility which is not desirable. Therefore the cobalt-titanium substitution for SrCoxTixFe12-2xO19 with X = 0.4 is the best to improve magnetic properties of strontium ferrite for various technical applications.REVIEWStrontium ferrite has been a subject of continuous interest and intensive study for several decades collect to the fact that this compound has been the the most widely used permanent magnet s, which account for about 90wt% of the annual production of permanent magnets since shortly after its discovery in the fifties. Strontium hexaferrite, SrFe12O19, is a ferrimagnet and is also know as ceramic permanent magnet. When compargond with alnico-magnets, strontium ferrite has advanced coercivity, moderate remenance, corrosion resistance and excellent chemical constancy 5. Iron(III) oxide (Fe2O3) is the principal components in SrFe12O19 which proves rise to its magnetic properties. Within the five different crystallographic sites of strontium ferrite, the iron ions atomic number 18 coupled antiferromagnetically. Due to its exalted magnetocrystalline anisotropy compass in its structure, SrFe12O19 exhibits mellow volume magnetic field strength and high coercivity 1. The high magnetic permeability in strontium ferrite enables it to store strong magnetic fields, which is stronger than iron. Strontium ferrite is often produced as nanoscale coat powder, which can be sin tered into solid cores.Strontium ferrite has been used for several important industrial applications, such as permanent magnets, microwave devices and high density perpendicular put down media, with proper doping in order to improve properties of strontium ferrite 1. SrFe12O19 has also been investigated as a medium for magnetic recording and magneto-optical recording and for long (millimetre)-wave devices 2. Efforts have made to the development of novel synthetic methods which facilitate the production of fine hexagonal ferrite particles and to possible ways of reducing their high subjective magnetocrystalline anisotropy.The objective in this study was to attempt the synthesis of cation substituted M-type hexagonal ferrite SrCoxTixFe12-2xO19 using the sol-gel method. The sol-gel method has been used widely to produce fine particles of a variety of oxides. The effect of doping strontium ferrite with cobalt (II) and titanium (IV) oxides to produce quaternary systems of SrO-Fe2O3-X O, where X represents the dopant cation would be tested. The fine particles of cation substituted ferrite produced by using sol-gel technique is desirable because the grain size of the materials used in magnetic recording is the main factor determining the level of background noise at grim density.Magnetic properties of strontium ferrite would be cerebrate in this study. Magnetic susceptibility balance would be used to charm the mass susceptibility for both strontium ferrite and cation-substituted strontium ferrite produced using the sol-gel method. The mass susceptibilities of the samples were comp atomic number 18d to determine the optimum amount of cation inevitable to dope to ferrite to give the best magnetic behaviour.CRYSTAL STRUCTURE OF M-TYPE HEXAGONAL SrFe12O19According to crystalline structure, hexaferrite can be sort out into four types, these include M, W, Y and Z types hexaferrites which correspond to (SrO + MeO)Fe2O3 ratios of 16, 38, 46 and 512 respectively. SrFe 12O19 is classified as M-type hexaferrite.The hexagonal SrFe12O19 was world-class prepared by Adelskold in 1938 2. He also confirmed that the crystal structure of this compound to be iso-structural with the naturally occurring ferrite mineral magnetoplumbite, and therefore it has the M-type structure. after structural refinements for strontium hexaferrite have confirmed his determination 2. Strontium ferrite is classified as hexagonal ferrite. It is denoted as having the space group P63/mmc. According to the research made by Kimura et al, the fretwork para grands measured are found to be a = 0.588 36nm and c = 2.303 76nm at room temperature 2.As shown for M-type hexaferrite BaFe12O19 in Fig. 1.1, the crystalline structures of different types of hexaferrites are remarkably complex. The building block cell contains ten oxygen degrees. A unit cell is sequentially constructed for four blocks, they are S (spinel), R (hexagonal), S* and R*. The S and R blocks have equivalent atomic arr angements and are rotated around the c- axis vertebra at 180 with respect to S* and R* blocks. R or R* block consists of three O2layers while S or S* block contains dickens O2layers with one oxygen site in the middle layer substituted by a Ba2+ion 16. The structure of strontium ferrite is similar to that of barium ferrite, by just substituting the barium ion with strontium ion.Fig.1.1Structure of barium hexaferriteOccasionally, a unit cell is comprises of two formula units. The unit cell consists of 64 ions per hexagonal unit cell, which are 2 strontium ions, 38 oxygen ions and 24 ferrous ions. The structure of magnetoplumbite are made of a layer of hexagonal close packed arrangement of oxygen and strontium ions, which is sandwiched between two spinal blocks containing a cubic close-packed arrangement of oxygen atoms with iron atoms.The iron atoms are positioned at five interstitial crystallographically different cation sites of the close-packed layers, videlicet 4f1 (tetrahedral site, A sites), 12k, 4f2, 2a (octahedral sites, B sites) and 2b (trigonal bipyramidal site) 15. The tetrahedral iron oxide is FeO4, octahedral iron oxide consists of six oxygen ions, which is FeO6, and the formula for trigonal bipyramidal iron oxide is FeO5. A schematic M-type structural representation and the five Fe3+ sites are shown in Fig. 1.2 by Collomb et al. 15.Figure 1.2 The crystal structure sketch map of the hexagonal M-type phase and the five Fe sites with their surroundings are displayed.The 2b sites only occur in the equivalent layer with strontium ion. 12k site is the octahedral site of S and R blocks. There are two tetrahedral (4f1) sites and one octahedral (2a) site in centre of S block. The two octahedral (4f2) sites are found in the R block, adjacent to the strontium-containing layer.The M-type structure of strontium ferrite gives rise to its magnetic properties. Cation substitution to strontium ferrite may give chances whereby altering the structure and thus infl uence the magnetic properties.MAGNETIC PROPERTIES OF M-TYPE HEXAGONAL SrFe12O19Strontium hexaferrite is a ferrimagnetic material. Since the free electrons in SrFe12O19 are in close proximity and remain align even the external magnetic field have been removed, it is able to retain a permanent magnetic field and is recognized as ferrimagnetic material.In 1950s Gorter predicted that the iron ions at the trigonal bipyramidal (2b) and octahedral (2a, 12k) sites have their spin orientation antiparallel to that of the iron ions at the 4f sites 2. The antiparallel 4f1 and 4f2 and parallel 2a, 12k and 2b sublattices form the ferrimagnetic structure. The magnetic ordering fit to the magnetoplumbite structure of hexagonal strontium ferrite is well illustrated in Fig. 1.3.In S block, the majority -sublattice consists of four octahedral ions and the minority -sublattice contains two tetrahedral ions whereas R block contributes three octahedral ions and one trigonal ion to the majority sublattic e and two octahedral ions to the minority sublattice.Figure 1.3 The schematic structure (left) of the SrFe12O19 with Gorters magnetic ordering (middle) along the c-axis. The extensive open circles are oxygen ions, the large broken circles are Sr ions small circles with a cross wrong represent Fe ions at 12k, small circles containing a filled circle inside represent Fe ions at 4f2, small unfilled circles represent Fe ions at 4f1, filled small circles represent Fe ions at 2a and small circles with a unfilled circle inside represent Fe ions at 2b. The magnetic structure suggested by Gorter is shown on the right, where the arrows represent the direction of spin polarization.From Fig. 1.3, we can summarizes the sites of Fe(III) ions jibe to the spin direction, as in Table 1.1.SiteCoordinationOccupancyDirection of spin polarization12kOctahedral12Up2aOctahedral2Up2bTrigonal Bypiramidal2Up4f1Tetrahedral4Down4f2Octahedral4DownTable 1.1 Fe(III) ion sites in M-type hexagonal ferriteHysteres is LoopThe magnetic properties of strontium ferrite can be examined through hysteresis eyelets. Hysteresis loop can be measured using instruments such as Vibrating Sample Magnetometer (VSM) and SQUID Magnetometry Measurements.When a magnetic material is placed in a magnetic field, the flux density (B) would lags behind the magnetizing force (H) that causes it, and this form hysteresis loop.From a hysteresis loop, we can identify the magnetic properties of the material, they are saturation magnetization, remanence or also cognize as remnant magnetization, and coercivity. A typical hysteresis loop is well illustrated in Fig. 1.4.Figure 1.4 Typical hysteresis loop (B-H curve)Initially, there is no applied magnetic field and it is known as unmagnetized state. After magnetic field is applied, it causes alignment. Until maximum magnetizing force applied, maximum flux density achieved at the same time and this phenomenon is known as saturation magnetization. At this point, the maximum num ber of spin has mobilized. Saturation magnetization is defined as the maximum possible magnetisation of a material. It is also a measure of strongest magnetic field a magnet can produce. The unit of saturation magnetization is in amperes per meter. Strontium ferrite is having high saturation magnetization at which it can store high amount of magnetizing force. As the magnetizing force being slowly removed, the alignment stays at the point where H = 0, this is known as remnant magnetization. Remnant magnetization is the magnetization left in a permanent magnet after an external magnetic field is removed. When a magnet is magnetized, it has remanence. It is usually measured in unit Tesla. Strong permanent magnet such as strontium ferrite has high remnant magnetization which means the high amount of magnetic force remains in it even after the magnetizing force is removed. As form Fig. 1.4, negative magnetic field is applied to erase the permanent magnet. When the flux density (B) = 0, there is no magnetizing force remain in the magnet and the negative H needed to demagnetize the magnet is known as coercivity. Negative H is the magnetic field applied in opposite direction. Coercivity is measured in unit amperes per meter. Due to its high uniaxial magnetocrystalline anisotropy with an easy axis of magnetization along the hexagonal c-axis in the structure, SrFe12O19 has high coercivity.Anisotropy is directional or orientational effects in crystal structure of materials which can provide better magnetic performance along certain preferred axis. Therefore, we need to book high negative magnetizing force to demagnetize strontium ferrite. Attempts have to be made to commence down the coercivity of strontium ferrite for usage.Units in MagnetismThe units used in magnetism can be divided mainly into two categories, SI system and c.g.s system. The conversion table shown in Table 1.2 is to clarify the magnetism formulas in both SI and c.g.s systems and the conversion fac tors between them.QuantitySymbolSI UnitSI Equationc.g.s Unitc.g.s EquationConversion FactorMagnetic InductionBtesla (T)B=o(H+M)gauss (G)B = H+4M1 T = 104GMagnetic Field StrengthHampere/meter(A/m)H = N-I/lc( lc magneticpath, m)oersted (Oe)H = 0.4N-I/lc(lc magneticpath, cm)1 A/m =4 -10-3OeMagnetic Fluxweber (Wb) = B-Ac(Ac area, m2)maxwell (M) = B-Ac(Ac area, cm2)1 Wb = 108MMagnetizationMampere/meter (A/m)M=m/V(m- total magnetic moment,V- volume, m3) emu/cm3M=m/V(m- total magnetic moment,V- volume, cm3)1 A/m = 10-3emu / cm3Magnetic Permeability of Vaccumonewton/ampere2o= 4-10-714-10-7InductanceL warmth contentL=oN2Ac/lc(Ac- area, m2,lc magnetic path, m)henryL=0.4N2Ac/lc-10-8(Ac-area, cm2,lc magnetic path, cm)1Emf (voltage)VvoltV=-N-d/dtvoltV=-10-8N-d/dt1Note In the above equations, I = current (in amps), N = turnsTable 1.2 Magnetism formulas in SI and c.g.s systems and their conversion factors for the magnetic units.1.4 PHOTOLUMINESCENCE PROPERTIES OF SrFe12O19According to the study of G. B. Teh et.al 3 on strontium ferrite, strontium ferrite was found to exhibit photoluminescence behavior. When a sample of strontium ferrite is excited at a certain wavelength, highest intensity of photoluminescence emission peaks was obtained. The ability of strontium ferrite to photoluminesce could be due to the oxygen vacancies in their lattice structure. The oxygen vacancies are assumed to cause the particles to exhibit photoluminescence behavior by acting as traps for mobile excitation. The oxygen vacancies have effective +2 charges, qualification them powerful electron capture centers. Valence electron would gain sufficient energy to jump from the valence band to the conduction band and leaving a gap known as hole during excitation. F-centers, which is the region where contain high amount of electrons would formed when the excited electrons being trapped in oxygen vacancies. These generative electron centers would lead to emission of luminescence when the holes and electrons recombine.1.5 SYNTHESIS ROUTE OF SrFe12O19The processing routes used for synthesis of strontium ferrite affect its properties much. Traditionally, this ferrite powder is synthesized by a sundry(a) oxide ceramic method, which involves the solid-state reaction between SrCO3 and Fe2O3 at a high calcination temperature (about 1300C). However, uncontrolled particle morphology, larger particle size and agglomerates would be the biggest disadvantages of this technique. Besides, contamination would be introduced to the sample while subsequent milling of the calcined ferrite powder and this would affect the magnetic properties become less desirable. Therefore, the narrowed particle size distribution, refined particle size and minimal particle agglomeration has been the main concern during the synthesis of strontium ferrite.In order to improve the magnetic properties, numerous nonconventional soft synthetic routes have been carried out, including sol-gel synthesis 3, hydrothermal reaction 6, co-precipitation 7, citric acid method 8 and microemulsion processing 10.In this study, the synthesis of strontium ferrite employed the sol-gel technique. It is a wet chemical route employing ethylene glycol as gel precursor. Sol-gel technique is the technique of using chemical substances which have high solubility in extreme solvents to synthesize precursor compounds. The compounds are well transformed into hydrous oxides on hydrolysis. The metal alkoxides formed can be removed easily using hydrolysis and thermal intercession and therefore results in hydrated oxides which are highly purify.Sol-gel method is used in this study because of its many advantages. Sol-gel technique is able to produce homogeneous nanosized crystallites. This method is tend to give shape materials directly from a solution without passing through the powder processing and the fact that the annealing temperature is very low compared with other conventional technology. The crystalline size and properties of the ferrite produced are largely affected by calcinations temperature 3. Sol gel method has the advantage that the crystal growth of particles is easier to control by varying the heat treatment 11. It was reported that at 500C it produced only maghemite, -Fe2O3. A mixed product of magnetic -Fe2O3 and M-type SrFe12O19 were obtained at 600C. As the calcination temperature increase to 800C and above, there are only M-type SrFe12O19 phase was observed. Sol-gel synthesis is able to produce high yields of SrFe12O19 nanoparticles. It is also able to produce nanocrystallite of cation substituted SrFe12O19. Nanoparticle size of strontium ferrite is desirable and aimed to synthesize because nanoparticles tend to give better magnetic properties. Nanoparticles give few magnetic bowls, probably single domain. Single domain tends to give higher magnetic induction because there are no oppose magnetic domain. Single domain aligns in one direction only. These properties are ideal for the making of permanent magnet.1.6 CATION SUBSTITUTION IN SrFe12O19In order to improve the magnetic properties of strontium ferrite, many studies have been carried out. One of them is cation substitution in strontium ferrite. Rare earth and other metal cations are used for substitution for strontium and iron respectively 5. The pair doping of SrFe12O19 such as a La-Co pair to replace a Sr-Fe pair has been tested 14. The doping, or known as cation substitution, is aim to improve the magnetic properties of strontium ferrite. Cation substitution results in structural changes in strontium ferrite. As the physical properties of ferrite change, the magnetic properties would be affected due to the fact that magnetic properties are determined by the arrangement of iron ions in crystal structure. In this study, Co-Ti pair will be doped to the strontium ferrite. Cobalt titanium substitution will produce a quaternary system of the type SrO-Fe2O3-AO where A represents the dopant cation.The cob alt titanium substitution gives rise to the new formula, SrCoxTixFe12-2xO19 where X is the number of seawalle of cation substituted in.1.7 Commercial ApplicationsStrontium ferrite is widely used as permanent magnet because it has direction of easy magnetization and the hexagonal c-axis which are perpendicular to the plane of the plate. The properties that are desirable in using as permanent magnet include high saturation magnetization, high remnant magnetization, high coercivity, high Curie temperature and high magnetocrystalline anisotropy.Besides, SrFe12O19 is also commonly used in high-density data storage magnetic recording media. Nanoparticles of SrFe12O19 with single domain and low coercivity are crucial in used for magnetic recording media. M-type strontium ferrite nanoparticles have attracted much attention due to their good frequency characteristic, low noise, high output, in particular, excellent high frequency characteristic and wide dynamic frequency range 4. There are two types of recording medium, namely particulates and thin films. Tape and floppy is categorized in particulate and hard drive is belongs to thin film. Information is stored by magnetizing material. The recording head can apply magnetic field (H) and align domains to magnetize the medium. It can also detect a change in the magnetization of the medium. Magnetic recording media prefers high saturation magnetization make it to store as much information. High value of remnant magnetization is required in recording media to make sure that all materials stored in the hard disk still remained even the power supply (applied magnetic field) is switched off. Low coercivity is important in magnetic recording media. When the positive magnetic field is applied, this charging manages the medium to store data. On the other hand, negative magnetic field applied to feel back the data, this is called discharges. Therefore, less current is needed to retrieve the data in the low coercivity medium. As a result, less heat generated and this saves the electricity.In general, strontium ferrite has high value of uniaxial anisotropy field, high coercive force and high saturation magnetization. The high coercivity of strontium ferrite has to be lowered down and saturation magnetization has to be simultaneously increased if it is to be useful for magnetic recording purposes. It has been reported that the substitution of cations such as Co(II) for the ion Fe(III) in strontium ferrite has lowered the coercive force. Therefore, many studies were carried out to achieve better magnetic properties of strontium ferrite for commercial applications.CHAPTER 2 EXPERIMENTALSample PreparationSynthesis of M-type SrFe12O19Synthesis of Cation Substituted SrFe12O19Sample CharacterizationMagnetic cleverness Balance MK12.1 Sample Preparation2.1.1 Synthesis of M-type SrFe12O19The sol-gel technique was used to synthesize M-type SrFe12O19 whereby the ethylene glycol acts as gel precursor. The starting mate rials, strontium nitrate, Sr(NO3)2 and iron(III) nitrate-9-hydrates, Fe(NO3)39H2O were used due to their high solubility in ethylene glycol. computer science below was made to determine the weight down of materials needed to be used.Relative Molecular bay window of materialsStrontium nitrate, Sr(NO3)2 = 211.63 g/ groinIron(III) nitrate-9-hydrates, Fe(NO3)39H2O = 404 g/mol(Note wholly answers have to be converted into 3 significant figures.)No. of mol of 1 g Sr(NO3)2 = Mass of Sr(NO3)2RMM of Sr(NO3)2= 1g211.63g/mol= 4.725210-3 molSr Fe = 1 12No. of mol of Fe(NO3)39H2O needed = 4.725210-3 mol x 12= 5.670210-2 molMass of Fe(NO3)39H2O needed = No. of mol of Fe(NO3)39H2O needed x RMM ofFe(NO3)39H2O= 5.670210-2 mol x 404g/mol= 22.9 gFrom the calculation, 1g of strontium nitrate and 22.9g of iron(III) nitrate-9-hydrates were needed in the synthesis and were weighted. Strontium nitrate would provided 1 mol of strontium ions and iron(III) nitrate-9-hydrates would provided 12 mol of iro n ions in the synthesis of strontium ferrite, which matched the molecular formula of SrFe12O19. The strontium nitrate and iron(III) nitrate-9-hydrates were readily dissolved in ethylene glycol with slight heat applied due to their high solubility in it. The mixture was heated slightly and stirred with a magnetic bar until the mixture was fully dissolved. The resolution solution is in transparent reddish color. The magnetic stirring bar was removed.The mixture was heated to 100C and it would slowly transform into a gel form. The gel was dried with continuous heating at 100C for 3 hours. The dried gel was then transferred to a crucible to remove traces of organic precursor. A mixture of metal oxides in dispersed nanoclusters form was obtained. The dried gel was then annealed in a furnace at 800C for 3 geezerhood with extensive ground with a pestle in a mortar after annealed at interval of each day.2.1.2 Synthesis of Cation Substituted SrFe12O19Cation substituted strontium ferrite wa s synthesized by using cobalt(II) ions and titanium(IV) ions to substitute the iron ions in M-type hexagonal strontium ferrite. The substitution of Co(II) and Ti(IV) gives the compound a new molecular formula, which is SrCoxTixFe12-2xO19 where the x denoted different ratios. In the synthesis of cation substituted SrFe12O19, the ratios of cations used, x, is in between 0.2 to 6.0 (0.2 x 6.0), where x = 0.2, 0.4, 0.6, 0.8, 1.0, 2.0, 3.0, 4.0, 5.0 and 6.0. The same method described in section 2.1.1 was used for the synthesis, by only adding two new starting materials, which are the cobalt(II) nitrate and titanium(IV) ethoxide to give the Co2+ and Ti4+ cations.Calculation as described below was made to calculate the weight of materials needed respectively.Relative Molecular Mass of materialsStrontium nitrate, Sr(NO3)2 = 211.63 g/molIron(III) nitrate-9-hydrates, Fe(NO3)39H2O = 404 g/molCobalt(II) nitrate, Co(NO3)2.6H2O = 291.04 g/molTitanium(IV) ethoxide, Ti(CC2H5)4 = 228.11 g/mol(Note All answers have to be converted into 3 significant figures.) voice used for the calculation SrCo0.2Ti0.2Fe11.6O19, x= 0.2No. of mol of 1 g Ti(CC2H5)4 = Mass of Ti(CC2H5)4RMM of Ti(CC2H5)4= 1g228.11g/mol= 4.383810-3 mol0.2 mol of Ti needed 1 mol of Sr.4.383810-3 mol of Ti needed (4.383810-3 mol x 1) mol of Sr.0.2Therefore, 0.021919 mol of Sr is needed.Mass of Sr(NO3)2 needed = 0.021919mol x 211.63 g/mol= 4.64 g0.2 mol of Ti needed 11.6 mol of Fe.4.383810-3 mol of Ti needed (4.383810-3 mol x 11.6) mol of Sr.0.2Therefore, 0.25426 mol of Fe is needed.Mass of Fe(NO3)39H2O needed = 0.25426mol x 404g/mol= 103 gMass of Co(NO3)2.6H2O needed = 4.383810-3 mol x 291.04g/mol= 1.28 gThe calculation above were used to calculate the weight of starting materials needed for other cation ratios, x for 0.4, 0.6, 0.8, 1.0, 2.0, 3.0, 4.0, 5.0 and 6.0 respectively as well. The weight needed for each material was tabulated in Table 2.1.xWeight of materials needed (g)Sr(NO3)2Fe(NO3)39H2OCo(NO3)2.6H2O0.24. 641031.280.42.3251.41.280.61.5531.91.280.81.1123.01.281.00.9317.71.282.00.467.081.283.00.313.541.284.00.231.771.285.00.190.711.286.00.150.001.28Table 2.1 Weight of materials needed for synthesis of Co(II)-Ti(IV) substituted strontium ferriteFor the series of different substitution ratios (x), the corresponding strontium nitrate, iron(III) nitrate-9-hydrates, cobalt(II) nitrate and titanium(IV) ethoxide were weighed and dissolved in 100ml ethylene glycol. The oxides obtained after ignition were then annealed in a furnace at 800C for 3 days with extensive ground with a pestle in a mortar after annealed at interval of each day. The preparation for strontium ferrite and cation substituted strontium ferrite is shown in Fig. 2.1 in flow chart array.Figure 2.1 Schematic diagram of the procedure for synthesis of strontium ferrite and cobalt-titanium substituted SrFe12O19.Sample CharacterizationMagnetic Susceptibility Balance MK1The magnetic properties of strontium ferrite and cobalt-titaniu m substituted strontium ferrite produced by the method described above were examined using the Magnetic Susceptibility Balance MARK 1 (MK1) by Sherwood Scientific Ltd, England. The magnetic susceptibility balance apparatus was shown in Fig. 2.2.Figure 2.2 Magnetic Susceptibility Balance MK1 by Sherwood Scientific Ltd, England.The basic design principle of Magnetic Susceptibility Balance MK1 was shown in Figure 2.3. Magnetic Susceptibility Balance determines the magnetic properties by placing two couple of moving magnets with the station in between where the stationary sample is ready to be measured. Basically, the possible deflection in the beam and the movement being made of a particular sample either solid or liquid could be observed in a equilibrate system which possesses a magnetic field. Meanwhile, the coil within the instrument is conducted with current required in order to make compensation of the magnetic force produced by the sample. Either paramagnetic or diamagnetic cou ld be resolved in a plus or minus relatively on display with the guardianship of the direction that the beam swifts.Figure 2.3 Basic design principle of Magnetic Susceptibility Balance MK1 by Sherwood Scientific Ltd, England.Magnetic susceptibility is defined as when the magnetising field is applied to the sample, how much is the ratio of the intensity of magnetism induced by the sample in response to the magnetising field which it is subject. In this experiment, mass susceptibility was the main concern. Mass susceptibility, xg, is defines by the mathematical formula belowg= v/dWhere d = density of substancev is the volume susceptibility, deliberate by using the formulav = I/